Effects of phosphate addition on the removal of disinfection by-product formation potentials by biological activated carbon filtration.

In drinking water treatment plants (DWTPs), the widely used biological activated carbon filters (BACFs), as the last barrier before disinfection, can remove dissolved organic matter (DOM) known as precursors of disinfection by-products (DBPs). Whether phosphate addition can improve water purification and DBP control of BACFs is still controversial. This study investigated short-term and long-term effects of phosphate addition on controlling DBP formation potentials (FPs) by BACFs via column and batch experiments. The BAC columns presented good water purification performance: they removed around 50 % DOM, nearly all fulvic acid-likes and humic acid-likes as well as 5 %-70 % chlor(am)innated THM4, HAA9 and HAN4 FPs (except chloraminated THM4 FPs)， which was mainly contributed by aerobic bacteria not anoxic bacteria. Phosphate addition within 7-14 days further improved removals of DOM, aromatic organics, fluorescence fractions in DOM as well as HAA9 and HAN4 FPs (especially TCAA FP and TCAN FP) to different extent. However, this improvement did not last longer, and removals of DOM, aromatic organics, two fluorescence fractions (soluble microbial byproduct-likes and humic acid-likes) and DBP FPs decreased despite long-term phosphate addition. Oxic and anoxic batch experiments showed that the positive response of water purification to short-term phosphate addition was also mainly attributed to aerobic bacteria and not to anoxic bacteria. For example, the former decreased DOM and DBP FPs, while the latter increased protein- and tryptophan-like substances as well as chloraminated THM4 FPs. Phosphate addition resulted in EPS increase in anoxic reactors and decrease in oxic reactors. These results indicated that a high dissolved oxygen in BACFs may be helpful for water purification and DBP control. Overall, short-term phosphate addition into phosphorus-limited water is beneficial for BACFs to control DBPs while long-term addition has no effect. Therefore, an intermittent phosphate addition into BACFs is suggested to control DBPs in DWTPs.

Predicting impacts of water conservation with a stochastic sewer model.

Population growth and climate change put a strain on water resources; hence, there are growing initiatives to reduce water use. Reducing household water use will likely reduce sewer input. This work demonstrates the use of a stochastic sewer model to quantify the effect water conservation has on sewer hydraulics and wastewater concentration. Probabilistic discharge patterns have been developed using SIMDEUM WW® and fed into hydraulic modelling software InfoWorks ICM® to produce likely flow and quality profiles for five future water use scenarios. The scenarios tested were developed to outline how commercial and political factors may change water use in future. Scenario testing revealed that 15-60% water reduction reflected a 1-48% drop in the morning peak flow. The water use reduction was predicted to increase wastewater concentrations of chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN) and total phosphorus (TPH) by 55-180%, 19-116% and 30-206% respectively. The sewer flow model was developed, calibrated and validated using a case study in the Wessex Water region of the UK and all future scenarios were compared to the validated baseline case. This wastewater flow and quality model allows scenario testing, which could help redesign future sewer networks to better prepare for water conservation strategies.